Product ID:AMMONIUM SULFIDE SOLUTION
MSDS Date:07/09/1987
FSC:6810
NIIN:00D005101
MSDS Number: BZNDX

MALLINCKRODT INC. SCIENCE PRODUCTS DIVISION

PARIS BYPASS
PARIS, KY 40361
US

Emergency Phone: 800-354-2050/314-982-5000

Info Phone: 800-354-2050(PRESS 3)/314-982-5000

Cage: 62910

MALLINCKRODT SPECIALTY CHEMICALS CO

PHILLIPSBURG, NJ 08865 US

Telephone: 908-859-2151

Cage: 62910

AMMONIUM SULFIDE (CERCLA)

CAS: 12135-76-1

RTECS: BS4920000

Fraction By Weight: 20-24%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

LD50 LC50 Mixture:NO LD50 INFO FOUND
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:IRRIT MUC MEMB.CONCEN OF
HYDROGEN SULFIDE >50PPM CAUSE HEAD,INSOMNIA,NAU,SORE
THROAT,DIZZ,DROWS,PULM EDEMA.INGEST:CORR TO GI TRACT THRU
LIBERATION OF HYDROGEN SULFIDE.VOMIT,HEAD,CYANOSIS,RESP DE
PRESS,BLOOD PRESSURE
FALL,UNCONSC,TREMORS,CONVULS,DEATH.SKIN/EYE:IRRIT,REDNESS,PAIN.CHRO
NIC:DMG EXPO TISSUES.
Effects of Overexposure:IRRIT MUC MEMBRANCE/EYE/SKIN. HEADACHE,
INSOMNIA, NAUSEA, SORE THROAT, DIZZINESS, DROWSINESS, PULMONARY
EDEMA. CORRO TO GI TRACT, VOMIT, CYANOSIS, RESP DEPRESSION, BLOOD
PRESSRUE FALL, UNCONSC, TREMOR S, CONVULSIONS, DEATH.
EYE/SKIN:REDNESS, PAIN. COUGHING, SHORTNESS OF BREATH.
Medical Cond Aggravated by Exposure:NO INFORMATION FOUND.

First Aid:INHAL:REMOVE TO FRESH AIR.ANY BREATH DIFFI GET MED ATTN.
INGEST:INDUCE VOMIT IMMED BY GIVING 2 GLASSES OF WATER & STICKING
FINGER DOWN THROAT.NEVER GIVE ANYTHING BY MOUTH IF UNCONSC.CALL
PHYSICIAN IMM ED. SKIN:REMOVE ANY CONTAMIN CLOTH.WSH W/PLENTY OF
WATER FOR @LEAST 15MINS.IRRIT DEVELOPS GET MED ATTN. EYE:WASH
W/PLENTY OF WATER FOR @LEAST 15MINS.IRRIT DEVELOPS GET MED ATTN.

Flash Point Method:CC
Flash Point:140F,60C
Extinguishing Media:DO NOT USE CARBON DIOXIDE AS FLAMM TOXIC HYDROGEN
SULFIDE GAS CAN BE GENERATED.ALCOHOL FOAM OR DRY CHEM MAY BE USED.
Fire Fighting Procedures:APPLY WATER FRM FAR DISTANCE AS POSSIBLE.USE
WATER IN FLOODING QUANT AS FOG:SOLID STREAMS OF WATER MAY BE
INEFFECTIVE TO KNOCK DOWN VAP.WEAR FULL PROT (SUPPLEM)
Unusual Fire/Explosion Hazard:NOT CONSIDERED EXPLO HAZ BUT CONTACT
W/POWERFUL OXIDIZERS MAY CAUSE EXPLO.

Spill Release Procedures:VENTILATE AREA. CLEAN-UP PERSONNEL REQUIRE
PORTECTIVE CLOTHING. CONTAIN & RECOVER LIQ WHEN POSSIBLE.LG:ABSORB
W/VERMICULITE,DRY SAND,EARY,OR SIMILAR MATL FOR DISPO AS HAZ WASTE
IN RCRA APPROVED FACILI TY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROTECT AGAINST PHSYICIAL
DMG.OUTSIDE/DETACHED STORAGE PREFERRED.INSIDE STORAGE SHOULD BE STD
FLAMM LIQ STORAGE RM/CABINET.
Other Precautions:REF:ACGIH DOC "INDUSTRIAL VENTI:MANUAL OF RECOMMENDED
PRAC".CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING
W/MATL.SEPARATE FROM ACIDS & OXIDIZING MATLS.STORAGE & USE AREAS
SHOULD BE NO SMOKING AREAS.

Respiratory Protection:IF TLV EXCEEDED DUST/MIST RESP W/CHEM GOGGLES
MAY BE WORN IN GENERAL UP TO 10X TLV.CONSULT RESPIRATOR SUPPLIER
FOR LIMITATIONS.ALTERNATIVELY SUPPLIED AIR FULL FACEPIECE RESP OR
AIRLINED HOOD MAY BE WO RN.
Ventilation:SYS OF LOC &/OR GEN EXHAU RECOMMENDED TO KEEP WORKER EXPO
BEL AEL.LOC EXHAU VENTI PREF-CAN CNTRL EMISSIONS OF (SUPPLEME)
Protective Gloves:PROTECTIVE GLOVES.
Eye Protection:CHEM SAF GOGGLES.
Other Protective Equipment:CLEAN BODY-COVERING CLOTHING.MAINTAIN EYE
WASH FOUNTAIN & QUICK-DRENCH FACILITIES IN WORKAREA.
Work Hygienic Practices:WASH CONTAMIN CLOTHH BEF REUSE. WASH AFT HNDLG.
Supplemental Safety and Health
FIREFIGHTING:CLOTH & NIOSH-APPROVED SCBA W/FULL FCPIECE OPERATED IN
PRESSURE DEMAND/OTHER POSITIVE PRESSURE MODE. VENTI:CONTAMINANT
@SOURCE,PREVENTING DISPERSION OF INTO GEN WORKAREA.

HCC:F4
Boiling Pt:B.P. Text:DECOMPOSES
Melt/Freeze Pt:M.P/F.P Text:NO INFO
Vapor Pres:NO INFO
Vapor Density:NO INFO
Evaporation Rate & Reference:NO INFO FOUND
Solubility in Water:INFINITE
Appearance and Odor:CLEAR, YELLOW LIQUID, STRONG CHARACTERISTIC ODOR.

Stability Indicator/Materials to Avoid:YES
CONTACT W/ACIDS MAY EVOLVE HYDROGEN SULFIDE. OXIDIZERS, ZINC.
Stability Condition to Avoid:MAY LOSE INTEGRITY W/AGE:MATL SLOWLY
PRODUCES HYDROGEN SULFIDE & AMMONIA IN PRESENCE OF MOISTURE.
Hazardous Decomposition Products:EMITS TOXIC FUMES OF SULFUR OXIDES,
NITRIC OXIDES, AND AMMONIA WHEN HEATED TO DECOMPOSITION.

Waste Disposal Methods:DO NOT FLUSH TO SEWER.RQ:100LBS.ENSURE
COMPLIANCE W/LOCAL, STATE AND FEDERAL REGULATIONS.

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particular situation.